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Manufacturer supply good quality Dimethyl itaconate 617-52-7 with stock
- Molecular Formula: C7H10O4
- Molecular Weight: 158.154
- Appearance/Colour: white crystalline low melting mass or liquid
- Vapor Pressure: 0.219mmHg at 25°C
- Melting Point: 37-41 °C(lit.)
- Refractive Index: 1.428
- Boiling Point: 207.999 °C at 760 mmHg
- Flash Point: 89.094 °C
- PSA： 52.60000
- Density: 1.084 g/cm3
- LogP: 0.27870
Dimethyl itaconate(Cas 617-52-7) Usage
|
Flammability and Explosibility |
Nonflammable |
|
Purification Methods |
Crystallise the ester from MeOH by cooling to -78o. [Beilstein 2 IV 2229.] |
|
General Description |
Dimethyl itaconate undergoes enantioselective Rh(I)-catalyzed hydrogenation which can be enhanced by appropriate choice of substituents on aromatic ring of (1,2-diarylphosphinoxy)cyclohexane. |
InChI:InChI=1/C7H10O4/c1-5(7(9)11-3)4-6(8)10-2/h1,4H2,2-3H3
617-52-7 Relevant articles
A short synthesis of (±)-methylenolactocin
Sarkar, Subrata,Ghosh, Subrata
, p. 4809 - 4810 (1996)
A short synthesis of the antitumor antib...
Redox silencing of the Fenton reaction system by an alkylitaconic acid, ceriporic acid B produced by a selective lignin-degrading fungus, Ceriporiopsis subvermispora
Ohashi, Yasunori,Kan, Yoshihiko,Watanabe, Takahito,Honda, Yoichi,Watanabe, Takashi
, p. 840 - 847 (2007)
The selective lignin-degrading fungus, C...
A concise synthesis of (±)-methylenolactocin and the formal synthesis of (±)-phaseolinic acid
Loh, Teck-Peng,Lye, Pek-Ling
, p. 3511 - 3514 (2001)
(±)-Methylenolactocin was prepared in fi...
Chemical synthesis, iron redox interactions and charge transfer complex formation of alkylitaconic acids from Ceriporiopsis subvermispora.
Enoki, Makiko,Honda, Yoichi,Kuwahara, Masaaki,Watanabe, Takashi
, p. 9 - 20 (2002)
In 1999, we first reported that a white ...
Phase-Transfer-Catalyzed Asymmetric Annulations of Alkyl Dihalides with Oxindoles: Unified Access to Chiral Spirocarbocyclic Oxindoles
Gao, Min,Hu, Lin,Li, Xuemin,Li, Yongyi
supporting information, p. 875 - 880 (2022/02/05)
A general phase-transfer-catalyzed asymm...
Synthesis and Bioactivity of Polymer-Based Synthetic Mimics of Antimicrobial Peptides (SMAMPs) Made from Asymmetrically Disubstituted Itaconates
Boschert, David,Schneider-Chaabane, Alexandra,Himmelsbach, Andreas,Eickenscheidt, Alice,Lienkamp, Karen
, p. 8217 - 8227 (2018/05/30)
A series of asymmetrically disubstituted...
Synthesis of functionalized 2-isoxazolines as three-dimensional fragments for fragment-based drug discovery
Tran, Ngoc Chau,Dhondt, Heleen,Flipo, Marion,Deprez, Benoit,Willand, Nicolas
supporting information, p. 4119 - 4123 (2015/08/03)
Abstract The design of new sp3 and spiro...
Esterification of itaconic acid using Ln～SO4 2-/TiO2-SiO2 (Ln = La3+, Ce 4+, Sm3+) as catalysts
Li, Lu,Liu, Shiwei,Xu, Junming,Yu, Shitao,Liu, Fusheng,Xie, Congxia,Ge, Xiaoping,Ren, Jianyun
, p. 24 - 30 (2013/04/10)
A series of itaconate esters, e.g. dimet...
617-52-7 Process route
-
-
67-56-1
methanol
-
-
97-65-4,25119-64-6
2-methylenesuccinic acid
-
-
617-52-7
Dimethyl itakonate
| Conditions | Yield |
|---|---|
|
With
La3+SO42-/TiO2-SiO2;
at 120 ℃;
for 7h;
Reagent/catalyst;
Time;
Concentration;
Autoclave;
|
93.07%
|
|
With
toluene-4-sulfonic acid; hydroquinone;
at 150 ℃;
for 1h;
|
90%
|
|
With
sulfuric acid;
Reflux;
|
72%
|
|
With
sulfuric acid;
for 6h;
Heating;
|
23.1 g
|
|
With
hydrogenchloride;
Heating;
|
|
|
With
sulfuric acid;
|
|
|
With
boron trifluoride;
at 100 ℃;
for 1h;
|
|
|
With
boron trifluoride;
at 100 ℃;
for 1h;
|
|
|
With
boron trifluoride;
|
-
-
97-65-4,25119-64-6
2-methylenesuccinic acid
-
-
74-88-4
methyl iodide
-
-
617-52-7
Dimethyl itakonate
| Conditions | Yield |
|---|---|
|
2-methylenesuccinic acid;
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
In
acetonitrile;
for 0.166667h;
methyl iodide;
In
acetonitrile;
at 20 ℃;
for 4h;
|
85%
|
617-52-7 Upstream products
-
97-65-4
2-methylenesuccinic acid
-
77-78-1
dimethyl sulfate
-
75-52-5
nitromethane
-
624-49-7
dimethylfumarate
617-52-7 Downstream products
-
64-18-6
formic acid
-
25306-99-4
dimethyl 2-(methoxymethyl)succinate
-
100911-29-3
methyl 1-ethyl-5-oxo-3-pyrrolidinecarboxylate
-
59857-84-0
methyl 1-(1-methylethyl)-5-oxo-3-pyrrolidinecarboxylate
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